Organic synthetic transformations using organic dyes as photoredox catalysts
نویسندگان
چکیده
منابع مشابه
Organic synthetic transformations using organic dyes as photoredox catalysts.
The oxidizing ability of organic dyes is enhanced significantly by photoexcitation. Radical cations of weak electron donors can be produced by electron transfer from the donors to the excited states of organic dyes. The radical cations thus produced undergo bond formation reactions with various nucleophiles. For example, the direct oxygenation of benzene to phenol was made possible under visibl...
متن کاملOrganic synthesis using photoredox catalysis
Natural photosynthesis is a remarkable chemical machinery that enables our life on earth and delivers a constant stream of oxygen and organic biomass. We should acknowledge this fact with humbleness, especially because we have not been able yet to mimic this process in a reliable way even after decades of intense research. The basic mechanistic principle behind photosynthesis is photoredox cata...
متن کاملOrganic Synthesis using Clay Catalysts
One of the major current challenges before chemists is to develop synthetic methods that are less polluting, i.e., to design clean or ‘green’ chemical transformations. The chemical manufacturing processes should be such that they do not cause permanent damage to the environment or disturb the ecological balance. Ways to minimize the consumption of energy and raw materials used in synthesis must...
متن کاملChemoselective Radical Dehalogenation and C-C Bond Formation on Aryl Halide Substrates Using Organic Photoredox Catalysts.
Despite the number of methods available for dehalogenation and carbon-carbon bond formation using aryl halides, strategies that provide chemoselectivity for systems bearing multiple carbon-halogen bonds are still needed. Herein, we report the ability to tune the reduction potential of metal-free phenothiazine-based photoredox catalysts and demonstrate the application of these catalysts for chem...
متن کاملPhotoredox Catalysis in Organic Chemistry
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In a general sense, these approaches rely on the ability of metal complexes and organic dyes to convert visible light into chemical energy by engaging in single-electron transfer with organic substrates, thereby generating reactive intermediates. In ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Org. Biomol. Chem.
سال: 2014
ISSN: 1477-0520,1477-0539
DOI: 10.1039/c4ob00843j